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High-Capacity Carboxylate-Functionalized Column for Disparate Sodium and Ammonium Concentrations
The IonPac® CS16 is the column of choice for disparate concentration ratios of adjacent eluting cations such as sodium and ammonium in diverse sample matrices. The high-capacity, high-resolution CS16 column can be used for short-chained amines, including alkylamines and alkanolamines, in diverse sample matrices. The CS16 column is now available in capillary format (0.5 × 250 mm) offering reduced eluent consumption and reduced operating costs.
For disparate concentration ratios of close-eluting cations such as ammonium and sodium in complex matrices
Ideal for trace-level ammonium in high concentrations of sodium
Ideal for trace-level sodium in high concentrations of ammonium or amines
Best carboxylate-functionalized column to tolerate samples with low pH
Isocratic acid eluent and elevated temperature (40 °C) required for sodium: ammonium ratios to 1:10,000
Gradient MSA eluent and elevated temperature required for sodium: ammonium ratios up to 1:20,000
Useful for short-chained amines, including alkylamines and alkanolamines
Compatible with organic solvents excluding alcohols
Using an isocratic acid eluent and elevated temperature (40 °C) coupled with suppressed conductivity, ratios up to 10,000:1 of sodium and ammonium can be resolved in less than 20 min. Sample matrices include environmental waters; power plant waters treated with ammonium, morpholine or ethanolamine; chemical additives; chemical process solutions; scrubber solutions; plating baths; and industrial solvents. The CS16 is designed for use in most IonPac CS15 applications.
The CS16 column has the highest capacity among Dionex carboxylate-based cation columns, resulting in improved loadability and resolution. Use the CS16 with the Eluent Generator for simplified, consistent methanesulfonic acid eluent preparation. Use the Cation Self-Regenerating Suppressor (CSRS® 300) with standard or microbore CS16 columns or the Cation Capillary Electrolytic Suppressor (CCES™ 300) with the CS16 capillary column.IonPac CS16 Cation-Exchange Column SpecificationsDimensionsIonPac® CS16 Capillary Column:
0.5 × 250 mm
IonPac CG16 Capillary Guard Column:
0.5 × 50 mm
IonPac CS16 Analytical Column:
5 × 250 mm and 3 × 250 mm
IonPac CG16 Guard Column:
5 × 50 mm and 3 × 50 mmMaximum Operating Pressure4000 psi (Standard and Microbore), 5000 psi (Capillary) Phase CompatibilityAcidic eluents; 0–* HPLC acetonitrile. Alcohols should be avoided.Substrate CharacteristicsBead Diameter: 5 µm
Cross-Linking (%DVB): 55%Functional Group CharacteristicsIon-Exchange Groups: Grafted carboxylic acid
Surface Characteristics: Medium hydrophobicCapacity84 µeq (0.5 × 250 mm capillary column)
17 µeq (0.5 × 50 mm capillary guard column)
8400 µeq (5 × 250 mm analytical column)
1700 µeq (5 × 50 mm guard column)
3000 µeq (3 × 250 mm analytical column)
600 µeq (3 × 50 mm guard column)Column ConstructionPEEK™ with 10-32 threaded ferrule-style end fittings.
All components are nonmetallic.